Colliders → Collision action matrix
=> It depends.
Some of the combinations only cause one of the two objects to be affected by the collision, but the general rule is that physics will not be applied to an object that doesn’t have a Rigidbody component attached.


You said
as the collider on the head won't use physics
But note that in general Collision = Physics.
So yes, at least one of the objects involved in a collision needs to be a (kinematic) Rigidbody.
As you can see in the matrix above e.g. for a collision with a static object the event (like OnCollisionEnter) will be invoked only on the object with a (kinematic o not) Rigidbody but not on the static object.
static here means it has no Rigidbody component attached even if it is moved by code or in other words: As soon as something moves in your scene it should have a (kinematic) Rigidbody component!
You can add colliders to a GameObject without a Rigidbody component to create floors, walls and other motionless elements of a Scene. These are referred to as static colliders. At the opposite, colliders on a GameObject that has a Rigidbody are known as dynamic colliders.