Gmail imposes a daily 500 recipient quota for sending emails. If you send through their POP/IMAP interface that quota is only 100 recipients per day.
What is the sending quota for sending an email on a gmail account using the google app engine? Would it follow the POP/IMAP limit or the standard gmail limit?
Here is all the official gmail quota information I found: http://mail.google.com/support/bin/answer.py?hl=en&answer=22839