There is a bit of a fudge you can do that will generate the output you need:

I am not aware of any way to only show the one line for your secondary axis, so what I have done instead is made sure that the different Series all have the same values so that the lines are all overlapping.
To do this, you will need to calculate the values for each of your Categories and repeat them for each row of your data that is a part of that Category. So if your January 2016
percentage needs to be 29%, make sure it is 29% for any record that is returning some data for January 2016
.
You can then set up your second Values
group to show the average
of this value, set it to show on the Secondary Axis and not show in the Legend, as this will get crowded. If you need to state what the line is, edit your Secondary Axis Title to be descriptive:

As you can see from my design view, I have actually set the Line to be the sum
of the Mon
Category Value (this value obviously being the same for each row in the same Category Group) which works in my example because my dataset requires no further aggregation. If you are summing up many rows to get the values in your chart, you will need to use average
.
This gives you what looks like just the one steadily increasing line on my chart, but is actually one line per Series all sitting on top of each other.