If you're using the ELM327, and you're on a protocol such as J1850 vpw, or J1850 pwm (older than 2003 CAN vehicles).. Then you will use this to set the header.
The header will consist of xx yy zz
xx = priority of message (i.e. 68)
yy = Target address of module you want to talk to (i.e. 5A)
zz = Sender address, which can usually be F1
So your command would look like this ATSH 68 5A F1
This sets the header.. Now you want to send data. Any data you send from now on will use that header, and send the data to that module.
So if you wanted to get the RPM's, you can just send 01 0C
You will get something like 41 0C 23. The last data byte is the value of RPM's. You will have to figure out the formula to convert this into a human readable format though.. A lot of information can be found here..
https://en.wikipedia.org/wiki/OBD-II_PIDs
By the way, if you're communicating on a CAN network, you would just use the module ID as the header.. ATSH 7E0, then send your data. all vehicles 2008+ are CAN.. some 2003-2007 are also.