This is a post to everyone who has ever asked himself "how do I maximize a window in my multi-screen setup without blocking the task bar".
The problem seems to be that a window that has MaximizeBox and MinimizeBox set to false and that gets maximized programmatically in a multi-screen environment covers the entire screen, not only the Screen.WorkingArea.
To maximize a window to the working area only, one needs to utilize the MaximizeBox and MinimizeBox properties like so:
// This code should be placed in the Form's ResizeEnd handler
MaximizeBox = MinimizeBox = true; // Enable both boxes
WindowState = FormWindowState.Maximized; // Set to maximized
MaximizeBox = MinimizeBox = false; // Disable both boxes again
Thus, the window will be nicely maximized on the screen and respect the screen's working area (not block the task bar).