It's not clear what you intended with the above code. If you were trying to load a text file and leave the loaded value in a variable called bootstrap-c-code, then try this:
(define bootstrap-c-code
(let ((from-file
(lambda (file-name)
(let* ((ip (open-input-file file-name))
(res (read-text-file-from-input-port ip)))
(close-input-port ip)
res))))
(from-file "llvm.c")))
Of course, the from-file definition will only be visible inside the let, if you need to use it outside, define it outside of the whole expression. If you only need the functionality of from-file inside the let, you can obtain the same result in a much simpler way:
(define bootstrap-c-code
(let* ((ip (open-input-file "llvm.c"))
(res (read-text-file-from-input-port ip)))
(close-input-port ip)
res))
On the other hand, if what you intended was to create a procedure called bootstrap-c-code, then the correct syntax would be:
(define (bootstrap-c-code)
(define (from-file file-name)
(let* ((ip (open-input-file file-name))
(res (read-text-file-from-input-port ip)))
(close-input-port ip)
res))
(from-file "llvm.c"))