I have next issue, why?
Below subquery produces more than one element
select item.quantity from unnest (_raw.line_items) as item
this is obvious - the output here has as many elements (rows) as many items in line_items array
So, to make your query work - you can simply add ARRAY in front of it - as in below example
SELECT
_raw.created_at,
_raw.name,
ARRAY(select item.quantity from unnest (_raw.line_items) as item) as quantity
FROM `Orders`
where DATE(_raw.created_at) = "2020-04-27"
OR make sure you limit output of subquery to just one element by adding LIMIT 1 as in below example
SELECT
_raw.created_at,
_raw.name,
(select item.quantity from unnest (_raw.line_items) as item LIMIT 1) as quantity
FROM `Orders`
where DATE(_raw.created_at) = "2020-04-27"
OR ... any other ways to restrict output of that subquery to only one element - which really depends on your specific use-case and what it is that you are trying to achieve
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