Keep in mind that the uri of the schema in the schemaLocation is resolved in the Schemas database, not on the web.
To be honest, I think it is easiest in MarkLogic to not use the xsi:schemaLocation attribute at all, and rather import the schema explicitly in xqy (using the import schema statement), to make sure it finds it correctly.
Joshua is right about Schematron by the way. The validate statement does not do Schematron validation. MarkLogic does provide schematron support however, which you could apply manually instead:
https://docs.marklogic.com/schematron
The pattern would roughly be as follows. You start with uploading schematron and schema into your schemas database. You then need to compile your schematron file using something like:
xquery version "1.0-ml";
import module namespace schematron = "http://marklogic.com/xdmp/schematron"
at "/MarkLogic/schematron/schematron.xqy";
schematron:put("/schematron.sch")
After that you use import schema and validate to do both schema and schematron validation. Something like:
import schema namespace mods = "http://www.loc.gov/mods/v3" at "/mods-3-6.xsd";
import module namespace schematron = "http://marklogic.com/xdmp/schematron"
at "/MarkLogic/schematron/schematron.xqy";
let $xml := <mods version="3.3" xmlns="http://www.loc.gov/mods/v3">
<titleInfo>
<title>FranUlmer.com -- Home Page</title>
</titleInfo>
<titleInfo type="alternative">
<title>Fran Ulmer, Democratic candidate for Governor, Alaska, 2002</title>
</titleInfo>
<name type="personal">
<namePart>Ulmer, Fran</namePart>
</name>
<genre>Website</genre>
<originInfo>
<dateCaptured point="start" encoding="iso8601">20020702 </dateCaptured>
<dateCaptured point="end" encoding="iso8601"> 20021203</dateCaptured>
</originInfo>
<language>
<languageTerm authority="iso639-2b">eng</languageTerm>
</language>
<physicalDescription>
<internetMediaType>text/html</internetMediaType>
<internetMediaType>image/jpg</internetMediaType>
</physicalDescription>
<abstract>Website promoting the candidacy of Fran Ulmer, Democratic candidate for Governor, Alaska, 2002. Includes candidate biography, issue position statements, campaign contact information, privacy policy and campaign news press releases. Site features enable visitors to sign up for campaign email list, volunteer, make campaign contributions and follow links to other internet locations. </abstract>
<subject>
<topic>Elections</topic>
<geographic>Alaska</geographic>
</subject>
<subject>
<topic>Governors</topic>
<geographic>Alaska</geographic>
<topic>Election</topic>
</subject>
<subject>
<topic>Democratic Party (AK)</topic>
</subject>
<relatedItem type="host">
<titleInfo>
<title>Election 2002 Web Archive</title>
</titleInfo>
<location>
<url>http://www.loc.gov/minerva/collect/elec2002/</url>
</location>
</relatedItem>
<location>
<url displayLabel="Active site (if available)">http://www.franulmer.com/</url>
</location>
<location>
<url displayLabel="Archived site">http://wayback-cgi1.alexa.com/e2002/*/http://www.franulmer.com/</url>
</location>
</mods>
return
schematron:validate(
validate strict { $xml},
schematron:get("/schematron.sch")
)
HTH!