Since you are able to use the web-interface, just log in. On the start page look for the server properties. Theres the version.
For upgrading follow these steps:
To stop openfire on ubuntu: /etc/init.d/openfire stop;
Backup copy of the openfire installation directory: /usr/share/openfire;
Backup Openfire Base in Postgres: If you use the pgAdmin application, right-click on openfire base and click “Backup”. To run backup, it can be with own postgres as user. I recommend tar format, and encoding “SQL_ASCII”.
To install the new version: you can actually use the “dpkg -i” command, you will be asked if you want to keep your current version (choose this one), but you will still upgrade (option N or O - keep your currently -installed version).
On the java, has a statement informing that from version 4.3 will be necessary Java 8 installed.
Source: https://discourse.igniterealtime.org/t/update-openfire-4-1-6-to-4-2-1-in-ubuntu-server/80336
And if you really meant the "XMPP-Version". There is not really such a thing. XMPP is implemented to a different extend on different server-providers. Some have more extensions, some less.
To see which ones you have, refer to the wikipedia site:
https://en.wikipedia.org/wiki/Comparison_of_XMPP_server_software