In windows server. C:/ Drive is the instance store and the rest of the other are EBS volume.
You can use boto3 to find all the Ebs volume attached to an instance.
Here is an example which will give you all the ebs volume attached to all the running instance in a region.
import boto3
session = boto3.Session(profile_name='Your_profile_name')
ec2 = session.resource('ec2')
for instance in ec2.instances.all():
if(instance.state['Name'] == "running"):
print(instance.id, instance.block_device_mappings)
You will get output something like this
('i-015XXXXXXXXXX', [{u'DeviceName': '/dev/xvda', u'Ebs': {u'Status': 'attached', u'DeleteOnTermination': True, u'VolumeId': 'vol-03cXXXXXXXXX', u'AttachTime': datetime.datetime(2019, 4, 17, 12, 23, 46, tzinfo=tzutc())}}])
('i-075XXXXXXXXXX', [{u'DeviceName': '/dev/xvda', u'Ebs': {u'Status': 'attached', u'DeleteOnTermination': True, u'VolumeId': 'vol-014XXXXXXXXX', u'AttachTime': datetime.datetime(2019, 4, 21, 10, 1, 40, tzinfo=tzutc())}}])