staring SQL from command line as a service, My instance name is SQL2K8R2 so below would be the command
Net Start MSSQL$SQL2K8R2 /m”SQLCMD”
If you have default instance than it would be "Net Start MSSQLServer /m”SQLCMD”"
Once you have started SQL Service in Single use mode then only SQLCMD application can connect and other connection would get error message.

2013-12-06 09:13:50.08 Server Registry startup parameters:
-d E:\Program Files\Microsoft SQL Server\MSSQL11.MSSQLSERVER\MSSQL\DATA\master.mdf
-e E:\Program Files\Microsoft SQL Server\MSSQL11.MSSQLSERVER\MSSQL\Log\ERRORLOG
-l E:\Program Files\Microsoft SQL Server\MSSQL11.MSSQLSERVER\MSSQL\DATA\mastlog.ldf
2013-12-06 09:13:50.08 Server Command Line Startup Parameters:
-s "MSSQLSERVER"
-m "SQLCMD"
…
2013-12-06 09:13:50.80 spid4s Warning ******************
2013-12-06 09:13:50.80 spid4s SQL Server started in single-user mode. This an informational message only. No user action is required.
….
2013-12-06 09:14:32.93 Logon Error: 18461, Severity: 14, State: 1.
2013-12-06 09:14:32.93 Logon Login failed for user ‘Contoso\demouser’. Reason: Server is in single user mode. Only one administrator can connect at this time. [CLIENT: <local machine>]