Basically, you could try to just change schema without reindexing, but that could cause nasty errors.
Quote from the official Solr guide:
When modifying the schema with the API, a core reload will
automatically occur in order for the changes to be available
immediately for documents indexed thereafter. Previously indexed
documents will not be automatically updated - they must be re-indexed
if existing index data uses schema elements that you changed.
If you modify your schema, you will likely need to re-index all
documents. If you do not, you may lose access to documents, or not be
able to interpret them properly, e.g. after replacing a field type.
Modifying your schema will never modify any documents that are already
indexed. You must re-index documents in order to apply schema changes
to them. Queries and updates made after the change may encounter
errors that were not present before the change. Completely deleting
the index and rebuilding it is usually the only option to fix such
errors.
multiValued=trueusing schema API. but you have to reindex docs, you can also check with partial update of document(updating a single field in the index). - Vinod