In general below is the difference between Network and Http load balancers.
Network Load balancer (layer 4):
This is the distribution of traffic based on network variables, such as IP address and destination ports. It is layer 4 (TCP) and below and is not designed to take into consideration anything at the application layer such as content type, cookie data, custom headers, user location, or the application behavior. It is context-less, caring only about the network-layer information contained within the packets it is directing this way and that.
Application load balancer (Layer 7)
This is the distribution of requests based on multiple variables, from the network layer to the application layer. It is context-aware and can direct requests based on any single variable as easily as it can a combination of variables. Applications are load balanced based on their peculiar behavior and not solely on server (operating system or virtualization layer) information.Provides the ability to route HTTP and HTTPS traffic based upon rules, host based or path based. Like an NLB, each Target can be on different ports.
The other difference between the two is important because network load balancing cannot assure availability of the application. This is because it bases its decisions solely on network and TCP-layer variables and has no awareness of the application at all. Generally a network load balancer will determine “availability” based on the ability of a server to respond to ICMP ping, or to correctly complete the three-way TCP handshake. An application load balancer goes much deeper, and is capable of determining availability based on not only a successful HTTP GET of a particular page but also the verification that the content is as was expected based on the input parameters.
Ref : https://medium.com/awesome-cloud/aws-difference-between-application-load-balancer-and-network-load-balancer-cb8b6cd296a4