Not much to go off of, but I would suggest recording your issue using SysInternals Process Monitor
Once you have procmon running, you want to record (or trace, in other words) your issue with VS2013. Once you're done recording, you'll want to filter the results by process (in your case, devenv.exe), so press Ctrl-T to open the Process Tree, and find devenv.exe.
Select it, and then click the "Include Subtree" button. Close the Process Tree window, and select Tools -> Count Occurrences from the top menu. Set the Column dropdown box to 'Result' and press the Count button. The output will be a collection of results along with their respective counts. You can usually get a good idea of what's going on by looking at these results. For example, if you see a lot of results involving ACCESS DENIED or FILE LOCKED WITH ONLY READERS, then most likely your issue is related to permissions.