You should provide more information about the data set features and the class distribution, this would help others to advice you.
In any case, I don't think a neural network fits here as this data set is too small for it.
Assuming 50% or more of the samples are of class 1 then I would first start by looking for a classifier that differentiates between class 1 and non-class 1 samples (binary classification). This classifier should outperform a naive classifier (benchmark) which randomly chooses a classification with a prior corresponding to the training set class distribution.
For example, assuming there are 1,000 samples, out of which 700 are of class 1, then the benchmark classifier would classify a new sample as class 1 in a probability of 700/1,000=0.7 (like an unfair coin toss).
Once you found a classifier with good accuracy, the next phase can be classifying the non-class 1 classified samples as one of the other 49 classes, assuming these classes are more balanced then I would start with RF, NB and KNN.