Alrighty, I promise this is the closest I'll ever get to a "code for me" question :) If this doesn't drum up any responses I'll bite the bullet and build an OTF parser to check for the existence of a CFF table.
This info is available in the Windows font preview ('TrueType outlines' vs 'PostScript outlines'), so presumably there's a WinAPI function to this effect, but damned if I can find it.
Thoughts anyone?
ps - It's not a dealbreaker if only installed fonts can be checked, but checking files would be preferable.