Supposing that you've a response like:
<Envelope xmlns="http://schemas.xmlsoap.org/soap/envelope/">
<Body>
<ns1:SampleTests xmlns:ns1="hola">
<ns1:SampleTest1>
<ns1:Test>1</ns1:Test>
</ns1:SampleTest1>
<ns1:SampleTest2>
<ns1:Test>2</ns1:Test>
</ns1:SampleTest2>
</ns1:SampleTests>
</Body>
</Envelope>
You can perform the follow XPath: exists(//*:Test[.=1]) to check that exists at least one <ns1:Test> element with 1 as value.
Inside an XPath Match it looks like:

If instead you prefer to use an Script assertion you can use the XmlSlurper to parse your Xml, then get all <ns1:Test> values an assert that at least one has 1 as value. Look into the follow code:
// get the response
def responseStr = messageExchange.getResponseContent()
// parse the response as slurper
def response = new XmlSlurper().parseText(responseStr)
// get all <ns1:Test> values
def results = response.'**'.findAll { it.name() == 'Test' }
// now in results list we've NodeChild class instances we will convert it to
// string in order to perform the assert
results = results.collect { it.toString() }
// check that at least one element has '1' value
assert results.contains('1'),'RESPONSE NOT CONTAINS ANY <ns1:Test>1</ns1:Test>'

exists(//ns1:SampleTests/ns1:SampleTest1/ns1:Test[ . = '1'])and expect it to betrue- Rao