Setup: Tomcat 7 Server, Eclipse Mars Milestone 3
The problem: When attempting to run Servlet files or connect to them the files 404. Although I can connect perfectly fine to JSP files it is just all servlet files which 404. Picture below.

Also should mention this effects all Servlets, not just one or two ALL.
I believe this is a local problem as a colleague is running the next same setup on another machine, although the servlet is successfully found.
This is the log from startup although no apparent error is show either on startup or on the load of a servlets url.
I'm using servlet mapping within the servlets to define the URL IE @WebServlet("/Sterling")
Question: What could be causing this and how can I fix it? Thank you.
Sep 30, 2015 10:21:29 AM org.apache.catalina.core.AprLifecycleListener init
INFO: The APR based Apache Tomcat Native library which allows optimal performance in production environments was not found on the java.library.path: C:\Program Files (x86)\Java\jre6\bin;.;C:\Windows\Sun\Java\bin;C:\Windows\system32;C:\Windows;C:/Program Files (x86)/Java/jre6/bin/client;C:/Program Files (x86)/Java/jre6/bin;C:/Program Files (x86)/Java/jre6/lib/i386;C:\Windows\system32;C:\Windows;C:\Windows\System32\Wbem;C:\Windows\System32\WindowsPowerShell\v1.0\;C:\Program Files\TortoiseSVN\bin;C:\Program Files (x86)\Micro Focus\RUMBA\;C:\Program Files (x86)\Micro Focus\RUMBA\System;C:\Eclipse;
Sep 30, 2015 10:21:30 AM org.apache.tomcat.util.digester.SetPropertiesRule begin
WARNING: [SetPropertiesRule]{Server/Service/Engine/Host/Context} Setting property 'source' to 'org.eclipse.jst.jee.server:{redacted}' did not find a matching property.
Sep 30, 2015 10:21:30 AM org.apache.coyote.AbstractProtocol init
INFO: Initializing ProtocolHandler ["http-bio-80"]
Sep 30, 2015 10:21:30 AM org.apache.coyote.AbstractProtocol init
INFO: Initializing ProtocolHandler ["ajp-bio-8009"]
Sep 30, 2015 10:21:30 AM org.apache.catalina.startup.Catalina load
INFO: Initialization processed in 1879 ms
Sep 30, 2015 10:21:30 AM org.apache.catalina.core.StandardService startInternal
INFO: Starting service Catalina
Sep 30, 2015 10:21:30 AM org.apache.catalina.core.StandardEngine startInternal
INFO: Starting Servlet Engine: Apache Tomcat/7.0.34
Sep 30, 2015 10:21:37 AM org.apache.coyote.AbstractProtocol start
INFO: Starting ProtocolHandler ["http-bio-80"]
Sep 30, 2015 10:21:37 AM org.apache.coyote.AbstractProtocol start
INFO: Starting ProtocolHandler ["ajp-bio-8009"]
Sep 30, 2015 10:21:37 AM org.apache.catalina.startup.Catalina start
INFO: Server startup in 6704 ms
Web.xml
<?xml version="1.0" encoding="UTF-8"?>
<web-app xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://java.sun.com/xml/ns/javaee" xsi:schemaLocation="http://java.sun.com/xml/ns/javaee http://java.sun.com/xml/ns/javaee/web-app_3_0.xsd" id="WebApp_ID" version="3.0">
<display-name>*****DataManagementTool</display-name>
<welcome-file-list>
<welcome-file>index.html</welcome-file>
<welcome-file>index.htm</welcome-file>
<welcome-file>index.jsp</welcome-file>
<welcome-file>default.html</welcome-file>
<welcome-file>default.htm</welcome-file>
<welcome-file>default.jsp</welcome-file>
</welcome-file-list>
</web-app>
Deployment Assembly Setup

urlPatterns={"/sterling"}- Joop Eggen