From 6.3.1.8/1 of the standard concerning integer conversions:
The integer promotions are performed on both operands. Then the following rules are applied to the promoted operands
If both operands have the same type, then no further conversion is
needed.
Otherwise, if both operands have signed integer types or both have
unsigned integer types, the operand with the type of lesser integer
conversion rank is converted to the type of the operand with greater
rank.
Otherwise, if the operand that has unsigned integer type has rank
greater or equal to the rank of the type of the other operand, then
the operand with signed integer type is converted to the type of the
operand with unsigned integer type.
Otherwise, if the type of the operand with signed integer type can
represent all of the values of the type of the operand with unsigned
integer type, then the operand with unsigned integer type is converted
to the type of the operand with signed integer type.
Otherwise, both operands are converted to the unsigned integer type
corresponding to the type of the operand with signed integer type.
In this case, the wrap-around is well defined. In the expression a-b, because both operands are of type unsigned char, they are first promoted to int and the operation is performed. If this value was assigned to an unsigned char, it would be properly truncated. However, you're passing this value to printf with a %x format specifier which expects an unsigned int. To display it correctly, use %hhx which expects an unsigned char.