Sidney Andrews posted an example at the following link of how to Configure the ASP.NET web.config file to setup the WCF service with the Service Bus Relay Endpoint.
https://gist.github.com/SidneyAndrewsOpsgility/bc1096ac96401f95b3d7
<?xml version="1.0" encoding="utf-8"?>
<!--
For more information on how to configure your ASP.NET application, please visit
http://go.microsoft.com/fwlink/?LinkId=169433
-->
<configuration>
<system.web>
<compilation debug="true" targetFramework="4.5.2"/>
<httpRuntime targetFramework="4.5.2"/>
</system.web>
<system.serviceModel>
<behaviors>
<serviceBehaviors>
<behavior name="">
<serviceMetadata httpGetEnabled="true" httpsGetEnabled="true"/>
<serviceDebug includeExceptionDetailInFaults="true"/>
</behavior>
</serviceBehaviors>
<endpointBehaviors>
<behavior name="ServiceBusBehavior">
<transportClientEndpointBehavior>
<tokenProvider>
<sharedAccessSignature keyName="RootManageSharedAccessKey" key="[replace with your key]" />
</tokenProvider>
</transportClientEndpointBehavior>
</behavior>
</endpointBehaviors>
</behaviors>
<serviceHostingEnvironment aspNetCompatibilityEnabled="true" multipleSiteBindingsEnabled="true"/>
<services>
<service name="WcfTest.Services.ClockService">
<endpoint address="" binding="basicHttpBinding" bindingConfiguration="DefaultBinding" contract="WcfTest.Services.IClockService"/>
<endpoint address="sb://[replace with your namespace].servicebus.windows.net/clock" binding="netTcpRelayBinding" behaviorConfiguration="ServiceBusBehavior" contract="WcfTest.Services.IClockService"/>
</service>
</services>
<bindings>
<basicHttpBinding>
<binding name="DefaultBinding" />
</basicHttpBinding>
<netTcpRelayBinding>
<binding name="ServiceBusBinding" />
</netTcpRelayBinding>
</bindings>
<extensions>
<!-- In this extension section we are introducing all known service bus extensions. User can remove the ones they don't need. -->
<behaviorExtensions>
<add name="connectionStatusBehavior"
type="Microsoft.ServiceBus.Configuration.ConnectionStatusElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="transportClientEndpointBehavior"
type="Microsoft.ServiceBus.Configuration.TransportClientEndpointBehaviorElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="serviceRegistrySettings"
type="Microsoft.ServiceBus.Configuration.ServiceRegistrySettingsElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
</behaviorExtensions>
<bindingElementExtensions>
<add name="netMessagingTransport"
type="Microsoft.ServiceBus.Messaging.Configuration.NetMessagingTransportExtensionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="tcpRelayTransport"
type="Microsoft.ServiceBus.Configuration.TcpRelayTransportElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="httpRelayTransport"
type="Microsoft.ServiceBus.Configuration.HttpRelayTransportElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="httpsRelayTransport"
type="Microsoft.ServiceBus.Configuration.HttpsRelayTransportElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="onewayRelayTransport"
type="Microsoft.ServiceBus.Configuration.RelayedOnewayTransportElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
</bindingElementExtensions>
<bindingExtensions>
<add name="basicHttpRelayBinding"
type="Microsoft.ServiceBus.Configuration.BasicHttpRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="webHttpRelayBinding"
type="Microsoft.ServiceBus.Configuration.WebHttpRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="ws2007HttpRelayBinding"
type="Microsoft.ServiceBus.Configuration.WS2007HttpRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="netTcpRelayBinding"
type="Microsoft.ServiceBus.Configuration.NetTcpRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="netOnewayRelayBinding"
type="Microsoft.ServiceBus.Configuration.NetOnewayRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="netEventRelayBinding"
type="Microsoft.ServiceBus.Configuration.NetEventRelayBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
<add name="netMessagingBinding"
type="Microsoft.ServiceBus.Messaging.Configuration.NetMessagingBindingCollectionElement, Microsoft.ServiceBus, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
</bindingExtensions>
</extensions>
</system.serviceModel>
</configuration>
Thanks Sidney, this is exactly what I needed!