For Spark 1.x, you can set with :
System.setProperty("hive.metastore.uris", "thrift://METASTORE:9083");
final SparkConf conf = new SparkConf();
SparkContext sc = new SparkContext(conf);
HiveContext hiveContext = new HiveContext(sc);
Or
final SparkConf conf = new SparkConf();
SparkContext sc = new SparkContext(conf);
HiveContext hiveContext = new HiveContext(sc);
hiveContext.setConf("hive.metastore.uris", "thrift://METASTORE:9083");
Update If your Hive is Kerberized :
Try setting these before creating the HiveContext :
System.setProperty("hive.metastore.sasl.enabled", "true");
System.setProperty("hive.security.authorization.enabled", "false");
System.setProperty("hive.metastore.kerberos.principal", hivePrincipal);
System.setProperty("hive.metastore.execute.setugi", "true");