I have a pie chart like this

However, I'd like it to look like this (i.e. left-aligned text, right aligned values within the label)

It doesn't seem possible in SSRS, which is a problem - can anyone help?
Sure it is!
Right click your series group -> Series Group Properties...
Insert the appropriate calculations into the label expression. I've done similar things like adding counts to the axis labels on bar charts.
EDIT: I feel like your best bet for these alignments is to create a small table next to the chart. It's an awkward solution, but here's an example I threw together to show it can kinda be done. You just have to make sure they are sorted the same. You can use a group + dataset to get your values. It's a very brittle fix, but it works.
