Like in almost any database driven application they're assigned in sequence. And no, you don't have to choose anything, it'll be taken care of by the framework. It needs to be unique, you can't add another user with the same ID and you must be sure that the user with this id will never be created in future. Thus: If you'd use an id that has already been given out, you'd have a duplicate. If you'd use one that has not yet been given out, you'll have a duplicate some time in future, when the sequence of ids comes to this value and the framework assigns the same id for the second time.
If you have an architecture that relies on a specific ID, your architecture is wrong. Rethink the problem and change the architecture and whatever you've already done to implement it.