Then can you explaing what you need to do exactly. Following your question you do not need to activate service. You can simple connect to that service. And there are 2 ways to do so.
The first way is to use native bluetooth communication (API). As there are at least 4 popular bluetooth stacks on Windows platform than first thing you have to do is decide whicb one is installed on your PC. Then you can use its API. They are all absolutely different. WCL and 32feet hides those differents from you and provides high level classes. Both have demo shows how to communicate with spp service. In WCL it is BluetoothClientDemo.
The second way is to use vCOM mechanism It is when you use Bluetooth drivers tool (on your picture it is ms add device dialog) to pair witb your device and connect to it. In this case a Bluetooth driver hides the connection under Virtual COM port which you can use then in your application. And again the low-level methods depend on driver used and are very fifferent. I am not sure if 32feet provides such functional but you can do it with WCL easy.
In both cases it is better to work with your device completly from your application. Because there is no easy way to find vCOM number for device installed by Bluetooth driver tool.
And I should repeat: yoj do not need to "activate" service. Think about it as about tcp services (ftp, smtp, http).
I hope this answered your question.