The November Guest OS release is targeted to support 4.5.2 out of the box, so no need to use start up task.
I believe you also need to upgrade to 2.6 sdk to be able to use 4.5.2.
http://sxp.microsoft.com/feeds/3.0/msdntn/WindowsAzureOSUpdates
On August 7, 2014, Microsoft announced that support will end for .NET
Framework 4, 4.5, and 4.5.1 on January 12, 2016. To ensure that your
cloud services continue to be secure and protected, Azure will update
the .NET Framework in Windows Azure Guest operating system (Guest OS)
family 2.x, 3.x and 4.x to .NET Framework 4.5.2 in November Guest OS
Release. Cloud services running on Guest OS family 2.x, 3.x and 4.x
with automatic updates enabled will be updated to the November Guest
OS with .NET Framework 4.5.2. If you have concerns of possible
application compatibility issues of the .NET update, we would suggest
you to validate your cloud service with .NET 4.5.2 before November
Patch Tuesday, Nov 10, 2015.
Update: something went wrong and Microsoft pushed this back to the January OS Family now.