For a start, you have the parameters to the functions reversed. Open() takes a char value less than 256, and Set() takes a 10-bit number.
That said, you have chosen the largest value (255) which gives the lowest frequency. As the datasheet explains, the Open() function takes a value for the period as the parameter. A higher frequency is equivalent to a shorter period, and vice versa.
Lastly, why would you want a duty cycle of 100%? That is the same as having the pin always high. In that case, frequency doesn't matter at all. Just turn the pin on and don't use PWM at all.
You haven't said what you are driving with this PWM, but generally speaking, having the frequency too high can cause problems. It can produce radio interference, overheat, and so on.
Your question indicates you misunderstand the purpose of PWM and what the terms refers to, so here is a tl;dr.
PWM simulates a voltage between 0 and Vcc by rapidly turning a pin high and low. The simulated voltage is proportional to the time_high/(time_high + time_low). The percent of time the pin is at Vcc is called the duty cycle. (So 100% duty is always on, giving Vcc volts. 0% duty is always off, giving 0 V.)
The rate at which this on/off cycle repeats is called the PWM frequency. If the frequency is too small (the period too long) the load will see the pin voltage fluctuating. The goal is to run the PWM fast enough to smooth out the voltage the load sees, but not so fast as to cause other problems. The available frequencies are appropriate for most applications. Also note that setting the frequency high (period small) will also reduce the accuracy of the duty cycle. This is explained in the datasheet. The reason is basically that the duty cycle must ultimately be converted to clock ticks on versus clock ticks off. The faster the frequency, the fewer ways to divide the clock ticks in each cycle.