See my answer at Widcomm bluetooth : how to open the virtual COM for my understanding of the licence: using the binary version is free for commercial use. And, also that I'm maintainer of the library.
So a brief slight digression. I'm not a big fan of virtual COM ports. It always seems much easier to use a direct 'sockets' connection, rather than attempt to setup a COM port, and try to find what name it was created as (see below!), and then have to open a SerialPort to use it, and then if the connection is lost one doesn't know and have simply to keep retrying... With the library its so much easier to just to create and use that direct Bluetooth connection!
However you may want a solution to your current task at the moment. :-) So, use WMI to find the current COM ports in place and see if any of them are for your device. For example in PowerShell:
C:\> Get-WmiObject -query "select DeviceID,PNPDeviceID from Win32_SerialPort"
...
...
DeviceID : COM66
PNPDeviceID : BTHENUM\{00001101-0000-1000-8000-00805F9B34FB}\7&1D80ECD3&0&00803A686519_C00000003
In that big long string one sees the address of the target device: 00803A686519. One can use WMI from .NET, run that query, filter the ones with "BTHENUM", and then parse out the address.
If you the do need to create a new Bluetooth virtual COM port, use 32feet.NET's BluetoothDeviceInfo.SetServiceState(BluetoothService.SerialPort) API. See the "Bluetooth Serial Ports" section in the User Guide e.g. at http://www.alanjmcf.me.uk/comms/bluetooth/32feet.NET%20--%20User%20Guide.html, and the class documentation in the release.
Unfortunately the native Win32 API we call does not tell what name of COM port it created! :-( So run the WMI query before and after the call to see what new name appeared (or use System.IO.Ports.SerialPort.GetPortNames as its simpler).
That's all specific to the Microsoft Bluetooth stack. I haven't investigated how other stacks behave in this regard. After a brief check Widcomm's serial ports appear in SerialPort.GetPortNames but not in the WMI query...