First of all those methods are not shows in the controller that means its in library section.
For your requirement you can create new or same methods in any of the controller If you use same methods like save(), delete() cancel() etc its will override the Joomla's default functions.
In your toolbar section you can have mention the function name as well.
JToolBarHelper::title('Yor custom component', 'head vmicon48'); //set title
JToolBarHelper::apply('saveConfig'); //when the apply button click its will call the saveConfig function the controller.
JToolBarHelper::cancel();
For some toolbar button argument order may different you can find here.
Also if you have more than one controller from your form you can mention the controller like as follows.
<input type="hidden" name="option" value="com_helloworld" />
<input type="hidden" name="view" value="yourview" />
<input type="hidden" name="task" value="my_controller_fun" />
<input type="hidden" value="your_controller_file_name" name="controller">
Hope you will get some idea !