According to Apple rules, it's allowed to use external payment methods like Paypal for goods and services "used outside of the application" or for "real-world services".
11.2 Apps utilizing a system other than the In-App Purchase API (IAP) to purchase content, functionality, or services in an App will be rejected
11.3 Apps using IAP to purchase physical goods or goods and services used outside of the application will be rejected
We have an Internet service with paid options, like Dropbox or Skype. The service can be used "outside the application" - in the literal sense of these words: it can be used with the iOS application or without it, inside or outside it.
The quesion is: are Internet services like Dropbox or Skype "real-world", so they can use Paypal as a payment method, or are they "unreal world", and should use In App Purchases?