Your picklist needs to point to a DualListModel...which itself contains a source list and a target list. So you need to create a source list and a target list and then create a DualListModel from them e.g. taking the primefaces showcase example:
List<Player> source = new ArrayList<Player>();
List<Player> target = new ArrayList<Player>();
source.add(new Player("Messi", 10, "messi.jpg"));
source.add(new Player("Iniesta", 8, "iniesta.jpg"));
source.add(new Player("Villa", 7, "villa.jpg"));
source.add(new Player("Alves", 2, "alves.jpg"));
source.add(new Player("Xavi", 6, "xavi.jpg"));
source.add(new Player("Puyol", 5, "puyol.jpg"));
listaMembros = new DualListModel<Player>(source, target);
Then your getter and setter would get and set a DualListModel...e.g
public DualListModel<Player> getListaMembros() {
return listaMembros;
}
public void setPlayers(DualListModel<Player> players) {
this.listaMembros = listaMembros;
}
Then in your xhtml the value of your picklist would be
#{usarioBean.listaMembros}
If your data within your lists is a complex type then you'll need to use a converter to convert the object