If you're accessing the EJB from a client within the same JVM as the EJB, the Remote interface is needless. The Remote interface is used by EJB clients that reside outside of the JVM in which the EJB is deployed. So in your particular case, all you'll need is
@EJB
private MyServiceBean myService;
Using the remote interface injection mechanism in your case would result in a needless roundtrip to arrive at the same result.
The use case for the different EJB invocation modes are
@Remote: Denotes a remote business interface. Method parameters are passed by value
and need to be serializable as part of the RMI protocol.(cited from Apress' beginning Java EE6 Platform)
@Local: Denotes a local business interface. Method parameters are passed by reference
from the client to the bean.(cited from Apress' beginning Java EE6 Platform)
None: This is the plain injection type where no interface is specified. Within the same JVM as the EJB, this is fine. From a design point of view (Loose coupling principle), you may want to use the @Local injection method