If you are using cross validation or grid search in scikit-learn then you can use multiple CPUs with the n_jobs parameter:
GridSearchCV(..., n_jobs=-1)
cross_val_score(..., n_jobs=-1)
Note that cross_val_score only needs a job per forld so if your number of folds is less than your CPUs you still won't be using all of your processing power.
LibSVM can use OpenMP if you can compile it and use it directly as per these instructions in the LibSVM FAQ. So you could export your scaled data in LibSVM format (here's a StackOverflow question on how to do that) and use LibSVM directly to train your data. But that will only be of benefit if you're grid searching or wanting to know accuracy scores, as far as I know the model LibSVM creates cannot be used in scikit-learn.
There is also a GPU accelerated version of LibSVM which I have tried and is extremely fast, but is not based on the current LibSVM version. I have talked to the developers and they say they hope to release a new version soon.
pragmadirectives in the source. Only thelibsvmwrapper seems to includeomp.hbut this looks more like template code as OpenMP is not used at all. - Hristo Iliev