The list of instance types that are built-in to OpsCenter are the ones they tested with at the time of the OpsCenter release. Amazon releases new instance types and those are not automatically available, but usually picked up in future OpsCenter releases.
There are two possible workarounds for getting the instance type/size you want, and still managing it through OpsCenter:
Launch new bare EC2 instances through the AWS console, then install Java on each. In OpsCenter choose Create Brand New Cluster, then choose the Local tab. You'll give the private IP addresses for each node and OpsCenter will install Cassandra/DataStax.
Launch new EC2 instances using the DataStax AMI and create your Cassandra cluster manually. Then once it's up and running go to OpsCenter and choose the Manage Existing Cluster option.
Option #2 is probably more manual work. You can see more details in the OpsCenter and Cassandra documentation.