[Django HTML template doesn't support index as of now], but you can achieve the goal:
If you use Dictionary inside Dictionary in views.py then iteration is possible using key as index. example:
{% for key, value in DictionartResult.items %} <!-- dictionartResult is a dictionary having key value pair-->
<tr align="center">
<td bgcolor="Blue"><a href={{value.ProjectName}}><b>{{value.ProjectName}}</b></a></td>
<td> {{ value.atIndex0 }} </td> <!-- atIndex0 is a key which will have its value , you can treat this key as index to resolve-->
<td> {{ value.atIndex4 }} </td>
<td> {{ value.atIndex2 }} </td>
</tr>
{% endfor %}
Elseif you use List inside dictionary then not only first and last iteration can be controlled, but all index can be controlled. example:
{% for key, value in DictionaryResult.items %}
<tr align="center">
{% for project_data in value %}
{% if forloop.counter <= 13 %} <!-- Here you can control the iteration-->
{% if forloop.first %}
<td bgcolor="Blue"><a href={{project_data}}><b> {{ project_data }} </b></a></td> <!-- it will always refer to project_data[0]-->
{% else %}
<td> {{ project_data }} </td> <!-- it will refer to all items in project_data[] except at index [0]-->
{% endif %}
{% endif %}
{% endfor %}
</tr>
{% endfor %}
End If ;)
//
Hope have covered the solution with Dictionary, List, HTML template, For Loop, Inner loop, If Else.
Django HTML Documentaion for more methods: https://docs.djangoproject.com/en/2.2/ref/templates/builtins/